Benzylic Lithium Compounds: The Missing Link in Carbon-Lithium Covalency. Dynamics of Ion Reorientation, Rotation around the Ring-Benzyl Bond, and Bimolecular …
G Fraenkel, K Martin
文献索引：Fraenkel, Gideon; Martin, Kevin V. Journal of the American Chemical Society, 1995 , vol. 117, # 41 p. 10336 - 10344
Abstract: Benzyllithium compounds, hitherto assumed from NMR data to consist of ion pairs, have been found to exhibit spin coupling between I3C and directly bound 6Li under conditions wherein bimolecular carbon-lithium bond exchange is too slow to average the coupling constants. These conditions involved the use of species in which lithium is internally solvated or of dilute solutions (0.005 M) of ben~ yllithium-I~ C-~ Li (enriched at ...
