Chemistry Letters

External heavy atom effect on intersystem crossing of radical pair in solvent cage. Photoreactions of phthalazine.

H Inoue, T Sakurai, T Hoshi, J Okubo, I Ono

文献索引：Inoue, Hiroyasu; Sakurai, Tadamitsu; Hoshi, Toshihiko; Okubo, Jun; Ono, Isao Chemistry Letters, 1990 , # 7 p. 1059 - 1062

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被引用次数: 3

摘要

External heavy atom effects have been studied for the photoreaction of phthalazine in 2- propanol. Addition of bromine containing compounds alters the product distribution in the dual photoreactions occurred simultaneously. The results can be interpreted in terms of enhancement of the intersystem crossing from the triplet radical pair to the singlet radical pair, including the spin inversion within the solvent cage.