Tetrahedron letters

A simple, effective, new, palladium-catalyzed conversion of enol silanes to enones and enals

RC Larock, TR Hightower, GA Kraus, P Hahn…

文献索引：Larock, Richard C.; Hightower, Timothy R.; Kraus, George A.; Hahn, Pat; Zheng, Deye Tetrahedron Letters, 1995 , vol. 36, # 14 p. 2423 - 2426

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被引用次数: 153

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Enol silanes derived from aldehydes and ketones are readily converted to the corresponding α,β-unsaturated carbonyl compounds by 10% Pd(OAc) 2 in the presence of one atmosphere of oxygen in DMSO as the solvent. ... Pd(OAc) 2 in DMSO under 1 atm. of O 2 catalyzes ...