Allylic Amination of Cyclohexene Catalyzed by Ruthenium Complexes. A New Reaction Involving an Inter molecular CH Functionalization

S Cenini, F Ragaini, S Tollari…

文献索引：Cenini, Sergio; Ragaini, Fabio; Tollari, Stefano; Paone, Daniele Journal of the American Chemical Society, 1996 , vol. 118, # 47 p. 11964 - 11965

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被引用次数: 77

摘要

Transition-metal-mediated intermolecular activation and functionalization of CH bonds is a topic of high current interest. From another perspective, the functionalization of a simple olefin by an external amine is also a topic that has attracted much interest. However, the direct intermolecular addition of an amine to an unactivated olefin, either metal-mediated or not, has met with only very limited success. 2 As far as allylic amines are considered as ...