Synthetic communications

Reductive Cleavage of S–S Bond by Zn/AlCl3 System: A Novel Method for the Synthesis of Sulfides from Alkyl Tosylates and Disulfides

B Movassagh, A Mossadegh

文献索引：Movassagh, Barahman; Mossadegh, Amir Synthetic Communications, 2004 , vol. 34, # 13 p. 2337 - 2343

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被引用次数: 15

摘要

Alkyl and aryl disulfides are reduced by zinc powder in the presence of AlCl 3 in aqueous media to yield zinc thiolates. These thiolate anion species then react with alkyl tosylates to give sulfides in high to excellent yields. ... Alkyl and aryl disulfides are reduced by zinc powder in the presence of AlCl 3 in aqueous media to yield zinc thiolates. These thiolate anion species then react with alkyl tosylates to give sulfides in high to excellent yields. ... Historically the chemistry of ...