Synlett

SiO2-TBD as New Heterogeneous Catalyst for the Nef Conversion of Secondary Nitroalkanes under Neat Conditions

…, D Fiorini, R Maggi, C Oro, A Palmieri, G Sartori

文献索引：Ballini, Roberto; Fiorini, Dennis; Maggi, Raimondo; Oro, Chiara; Palmieri, Alessandro; Sartori, Giovanni Synlett, 2006 , # 12 p. 1849 - 1850

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被引用次数: 3

摘要

A few years ago our group reported a selective Nef transformation of secondary nitroalkanes into the corresponding ketones under basic conditions, with the help of DBU as base and acetonitrile as solvent. [8] However, all the above procedures are usually carried out under homogeneous conditions by using an appropriate solvent in which both the starting materials and the catalyst are soluble and consequently catalyst recovery and reuse is difficult or impossible. With ...