Organoboron Compounds. I. The Preparation of 2-Chlorovinyl-and 2-Chlorovinylethylboranes by Vinylation, Disproportionation and Exchange Reactions1

E GIPSTEIN, PR KIPPUR, MA HIGGINS…

文献索引：Gipstein,E. et al. Journal of Organic Chemistry, 1961 , vol. 26, p. 2947 - 2950

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被引用次数: 6

摘要

The alkylhaloboranes are versatile intermediates which can be utilized for the preparation of many organoboron compounds containing one, two, or three boron-carbon bonds. The halides are very reactive and readily undergo reactions in which the halogen is replaced without affecting the boron-carbon bonds. In general, synthetic routes to alkylhaloboranes require the use of metals, metal alkyls, or Grignard reagentsa2 It was the purpose of this ...