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Tetrahedron Letters

Iodolactonization and iodoetherification of β, γ-unsaturated acids and alcohols using FeCl 3 and NaI

SP Chavan, AK Sharma

文献索引:Chavan, Subhash P; Sharma, Anil K Tetrahedron Letters, 2001 , vol. 42, # 29 p. 4923 - 4924

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被引用次数: 24

摘要

Iodolactonization and iodoetherification are crucial reactions in organic synthesis as well as in structure elucidation. Iodolactonization was utilized elegantly for stereoselective functional group incorporation and manipulation in Corey's prostaglandin synthesis 1 as well as in total syntheses of tumor inhibitors eg vernolepin and vernomenin 2 and in vitamin D 2 and D 3 3 synthesis. Likewise iodoetherification has been used in important organic syntheses eg of ...