Journal of fluorine chemistry

Reaction of methanol with perfluorotetracyclobuta-1, 3, 5, 7-cyclo-octatetraene

WR Cullen, SJ Rettig, AE Moore, RL Soulen

文献索引：Cullen, William R.; Rettig, Steven J.; Moore, Alice E.; Soulen, Robert L. Journal of Fluorine Chemistry, 1996 , vol. 76, # 2 p. 121 - 124

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被引用次数: 4

摘要

Perfluorotetracyclobuteno-1, 3, 5, 7-cyclooctatetraene (PCOT) is a planar and centrosymmetric molecule which possesses an extraordinary electron affinity due to the planarity of the eight π-electron system and the cumulative electron-withdrawing effects of the 16 fluorine atoms. An improved method for the synthesis of PCOT and the product resulting from the spontaneous reaction of PCOT with excess alcohol is reported. Crystal ...