A Novel and Efficient Method for the Preparation of. ALPHA.-Hydroxyimino Carbonyl Compounds from. ALPHA.,. BETA.-Unsaturated Carbonyl Compounds with Butyl …
K Kato, T Mukaiyama
文献索引：Kato, Koji; Mukaiyama, Teruaki Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 10 p. 2948 - 2953
Various α, β-unsaturated carbonyl compounds, such as α, β-unsaturated esters, α, β- unsaturated ketones, α, β-unsaturated nitriles, and α, β-unsaturated amides, were directly converted to the corresponding a-hydroxyimino carbonyl compounds in high yields on treatment with butyl nitrite and phenylsilane in the presence of a catalytic amount of N, N′- bis (2-ethoxycarbonyl-3-oxobutylidene) ethylenediaminatocobalt (II) complex under mild ...
