Journal of Inorganic and Nuclear Chemistry

The preparation of tellurium perfluoroalkyls by photolysis of dimethyltelluride in the presence of perfluoroalkyl iodides

ML Denniston, DR Martin

文献索引：Denniston; Martin Journal of Inorganic and Nuclear Chemistry, 1975 , vol. 37, p. 1871

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被引用次数: 19

摘要

Abstract The following new compounds containing perfluoroalkyl-tellurium linkages have been synthesized: CH 3 TeCF 3,(CF 3) 2 Te, CH 3 TeC 2 F 5,(C 2 F 5) 2 Te. These preparations were brought about by the photochemical interaction of (CH 3) 2 Te and an appropriate perfluoroalkyl iodide in a vycor tube at 310 nm wavelength. The resulting mixture of tellurides, R f TeCH 3 and (R f) 2 Te in which R f= CF 3 or C 2 F 5, cannot be ...