Phosphorus, Sulfur, and Silicon

Synthesis and properties of the first disulfur and diselenium complexes of platinum

N Tokitoh, K Nagata, N Takeda

文献索引：Tokitoh, Norihiro; Nagata, Kazuto; Takeda, Nobuhiro Phosphorus, Sulfur and Silicon and the Related Elements, 2004 , vol. 179, # 4-5 p. 915 - 927

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被引用次数: 3

摘要

The reactions of overcrowded platinum (0) complexes [Pt {P (Ar) Me2} 2](Ar= 2, 4, 6-tris [bis (trimethylsilyl) methyl] phenyl (Tbt), 2, 6-bis [bis-(trimethylsilyl) methyl]-4-[tris (trimethylsilyl) methyl] phenyl (Bbt)) with elemental sulfur and selenium resulted in the formation of the first platinum disulfur and diselenium complexes,[Pt (S2){P (Ar) Me2} 2](4a (Ar= Tbt), 4b (Ar= Bbt) and [Pt (Se2){P (Ar) Me2} 2](5a (Ar= Tbt), 5b (Ar= Bbt)) respectively. The x-ray ...