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Organoelement Complexes of a Dinucleating Double β??Diiminato Ligand–Precedent Cases from Groups 1, 2, and 13

JP Falkenhagen, P Haack, C Limberg…

文献索引:Falkenhagen, Jan P.; Haack, Peter; Limberg, Christian; Braun, Beatrice Zeitschrift fur Anorganische und Allgemeine Chemie, 2011 , vol. 637, # 12 p. 1741 - 1749

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被引用次数: 3

摘要

Abstract Main group chemistry of dinucleating ligands based on a xanthene backbone and two parallel diiminato binding sites (Xanthdim) has been investigated. To complement studies concerning the coordination modes adopted by Xanthdim in combination with alkali metal ions a di-rubidium complex with toluene co-ligands has been prepared. Its structural parameters lie in between those previously observed for corresponding K+ and Cs+ ...