Electrochemical reduction and oxidation of cobalt (III) dithiocarbamates

AM Bond, AR Hendrickson, RL Martin, JE Moir…

文献索引：Bond, A. M.; Hendrickson, A. R.; Martin, R. L.; Moir, J. E.; Page, D. R. Inorganic Chemistry, 1983 , vol. 22, p. 3440 - 3446

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被引用次数: 26

摘要

The literature describing the oxidation and reduction of cobalt (II1) dithiocarbamate complexes, Co (R, dtc),, and the chemistry of formally cobalt (I1) and cobalt (1V) dithiocarbamate complexes contains substantially conflicting data. An extensive investigation of the electrochemical reduction and oxidation of Co (R2dtc), leads to the following conclusions:(i) In CH2CI2 and for R= cyclohexyl, controlled-potential oxidative ...