Trifluoromethyl hydroperoxide. Properties and reactions with some acid fluorides

DD DesMarteau, PA Bernstein…

文献索引：Bernstein,P.A. et al. Journal of the American Chemical Society, 1971 , vol. 93, p. 3882 - 3886

全文：HTML全文

被引用次数: 2

摘要

Abstract: A convenient preparation of trifluoromethyl hydroperoxide, CF300H, is described and its physical and chemical properties are reported. Trifluoromethyl hydroperoxide behaves as a weak protic acid and readily forms trifluoromethyl peroxides with a variety of reactants. With acid fluorides trifluoromethylperoxy esters are formed in high yield. The synthesis and properties of the new compounds CFsC (0) OOCF3, CH3C (0) OOCF8, CF~ ...