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Dilithiation of aromatic ethers

GP Crowther, RJ Sundberg…

文献索引:Crowther, G. P.; Sundberg, Richard J.; Sarpeshkar, Ashok M. Journal of Organic Chemistry, 1984 , vol. 49, # 24 p. 4657 - 4663

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被引用次数: 59

摘要

Results We report here the results of attempts to prepare the dilithium derivatives of anisole, and the isomeric di-and trimethoxy derivatives of benzene. We were primarily interested in preparing these intermediates by direct dilithiation, but in those cases where the dilithio intermediates could not be prepared directly or where there was some question concerning their stability or substitution pattern, halogen-lithium exchange was used. In general, the ...