Polymer-supported sulfinimidoyl chlorides: A convenient reagent for oxidation of alcohols

…, A Kawana, H Yamanaka, H Kamiyama

文献索引：Matsuo, Jun-ichi; Kawana, Asahi; Yamanaka, Hiroyuki; Kamiyama, Hiroaki Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 7 p. 1433 - 1440

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被引用次数: 8

摘要

Two polymer-supported sulfinimidoyl chlorides, ie, 4-(N-tert-butylchlorosulfinimidoyl) phenoxymethylpolystyrene (3) and 4-(N-tert-butylchlorosulfinimidoyl) polystyrene (10), were prepared from chloromethylpolystyrene and polystyrene, respectively. Stoichiometric or catalytic oxidation of various primary and secondary alcohols using these polymer- supported sulfinimidoyl chlorides proceeded smoothly, and the corresponding aldehydes ...