Tetrahedron

Benzylation of benzene and alkylbenzenes at low temperatures

P Finocchiaro

文献索引：Finocchiaro,P. Tetrahedron, 1971 , vol. 27, p. 581 - 591

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被引用次数: 4

摘要

Reactivity of benzene and certain alkylbenzenes (toluene, p-xylene, mesitylene) during benzylation with benzylchloride and some derivatives (α-chloroethylbenzene, benzhydrylchloride, chloromethylmesitylene) has been determined under non-isomerizing conditions, in the temperature range− 10° and− 120°, in ethyl chloride solution with AlCl3 as a catalyst. Steric effects are found to play a major role in the reactivity when benzylchloride ...