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Syntheses and Properties of Dimethyl and Tetramethyl Anthra (1, 9-cd: 4, 10-c'd') bis (1, 2) dichalcogenoles and Their Charge-Transfer Complexes.

K Takimiya, Y Aso, T Otsubo, F Ogura

文献索引:Takimiya, Kazuo; Aso, Yoshio; Otsubo, Tetsuo; Ogura, Fumio Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 7 p. 2091 - 2102

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被引用次数: 17

摘要

The dimethyl and tetramethyl derivatives of a series of anthra [1, 9-cd: 4, 10-c′ d′] bis [1, 2] dithiole, diselenole, and ditellurole have been prepared as a new type of electron donor. The introduced methyl groups serve to enhance not only the donor strength, but also the solubility, enabling a ready formation of their charge-transfer complexes with various electron acceptors such as 7, 7, 8, 8-tetracyanoquinodimethane (TCNQ), its 2, 3, 5, 6- ...