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Applied Catalysis A: General

High-performance ring-opening catalysts based on iridium-containing zeolite Beta in the hydroconversion of decalin

D Santi, T Holl, V Calemma, J Weitkamp

文献索引:Santi, Dominic; Holl, Tobias; Calemma, Vincenzo; Weitkamp, Jens Applied Catalysis A: General, 2013 , vol. 455, p. 46 - 57

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被引用次数: 23

摘要

Decalin was converted in a flow-type reactor under a hydrogen pressure of 5.2 MPa on Ir/H, A-Beta zeolite catalysts, where A stands for an alkali metal cation. In one series of catalysts, the Ir content was 3wt.%, and the nature of A was varied from lithium to cesium. In a second series, the iridium content in Ir/H, Cs-Beta was varied from 1 to 5wt.%. On some of these catalysts, open-chain decanes (OCDs) were formed with unprecedented selectivities and ...