Synthesis, characterisation and reactivity of novelbis (tosyl) imidoruthenium (vi) porphyrin complexes; X-ray crystal structureof a tosylamidoruthenium (iv) porphyrin

…, WH Fung, MC Cheng, CM Che, SM Peng

文献索引：Au, Sze-Man; Fung, Wai-Hong; Cheng, Ming-Chuan; Che, Chi-Ming; Peng, Shie-Ming Chemical Communications, 1997 , # 17 p. 1655 - 1656

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被引用次数: 34

摘要

Bis (tosyl) imidoruthenium (VI) porphyrin complexes are prepared and characterised by spectroscopic means;[Ru VI-(tpp)(NTs) 2] can undergo imido group transfer reactions with alkenes to afford aziridines, as well as C–H bond oxidation of benzyl alcohol to give benzaldehyde; a tosylamido ruthenium (IV) complex is also isolated and characterised by X- ray diffraction.

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