Esr detection of alkylideneamino radicals in the reaction of nitrogen atoms with alkenes

PJ Brooke, B Mile

文献索引：Brooke, Peter J.; Mile, Brynmor Journal of the Chemical Society, Chemical Communications, 1980 , # 9 p. 395 - 396

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摘要

Intermediates formed in the gas-phase reaction of nitrogen atoms with alkenes have been trapped in an inert matrix using a rotating cryostat; esr examination of the frozen samples has shown the presence of methyleneamino (CH2N·) and alkylideneamino (RCHN·) radicals.