Syntheses, Crystal Structures, and DNA Bindings of Co (III) and Ni (II) Complexes Based on 2, 6-Bis (benzimidazol-2-yl)-4-hydroxypyridine Ligand

LZ Yuan, Q Ge, XF Zhao, Y Ouyang, SH Li…

文献索引：Yuan, Ling-Zhi; Ge, Qiang; Zhao, Xiao-Fei; Ouyang, Yan; Li, Shao-Hua; Xie, Cheng-Zhi; Xu, Jing-Yuan Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2014 , vol. 44, # 8 p. 1175 - 1182

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摘要

The ligand 2, 6-bis (benzimidazol-2-yl)-4-hydroxypyridine (H3OBP) and its complexes,[Co (HOBP)(H2OBP)]· 2H2O· 2EtOH (1) and [Ni (H2OBP) 2][Ni (H3OBP)(H2OBP)] NO3· 3H2O (2), have been synthesized and characterized by single-crystal X-ray crystallography, IR, UV- Vis, and fluorescence spectroscopies. Each metal center in two complexes is six- coordinated with N6 donor set in slightly distorted octahedral environment, which are ...