Stereoselective Control by Face??to??Face Versus Edge??to??Face Aromatic Interactions: The Case of C3??TiIV Amino Trialkolate Sulfoxidation Catalysts

…, M Bonchio, WA Nugent, C Zonta…

文献索引：Santoni, Gabriella; Mba, Miriam; Bonchio, Marcella; Nugent, William A.; Zonta, Cristiano; Licini, Giulia Chemistry - A European Journal, 2010 , vol. 16, # 2 p. 645 - 654

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被引用次数: 22

摘要

Abstract The stereoselective oxidation of differently functionalised benzyl phenyl sulfides has been examined by using enantiopure Ti IV trialkanolamine complexes. These complexes efficiently catalyse the sulfoxidation with good stereoselectivities. The data highlight the contribution to the stereoselectivity of steric effects and non-covalent π–π interactions between the aromatic rings of the Ti IV complex and those pertaining to the ...