Synthesis of 1, 4-Dioxa-2. lambda. 5-phosphorinanes by Insertion of Triphenylalkylidenephosphoranes into the Peroxide Bond of 1, 2-Dioxetanes: Thermolysis, …
W Adam, HM Harrer, A Treiber
文献索引：Adam, Waldemar; Harrer, Heinrich M.; Treiber, Alexander Journal of the American Chemical Society, 1994 , vol. 116, # 17 p. 7581 - 7587
Abstract: The reaction of the methyl-substituted 1, 2-dioxetanes 1-3 with triphenylalkylidenephosphoranes 4-7 was investigated. By nucleophilic attack of the negatively charged phosphorane carbon atom at the peroxide bond of the 1, 2-dioxetanes, the dipolar phosphonium alkoxides 8-13 were formed, which were in equilibrium with the ring-closed 2, 2, 2-triphenyl-1, 4-dioxa-2X~-phosphorinanes 14-19. Hydrolysis of the ...
[Chen, Xiangning; Hortelano, Edwin R.; Eliel, Ernest L.; Frye, Stephen V. Journal of the American Chemical Society, 1992 , vol. 114, # 5 p. 1778 - 1784]
