Synthesis of tris (β, β, γ-oximinoalkyl) amines from aliphatic nitro compounds and methyl vinyl ketone

EA Shalamova, Y Lee, G Chung, AN Semakin, J Oh…

文献索引：Shalamova, Elena A.; Lee, Yeosan; Chung, Garam; Semakin, Artem N.; Oh, Jinho; Sukhorukov, Alexey Yu.; Arkhipov, Dmitry E.; Ioffe, Sema L.; Semenov, Sergey E. Tetrahedron Letters, 2014 , vol. 55, # 6 p. 1222 - 1225

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被引用次数: 2

摘要

Abstract A general strategy for the assembly of previously unknown tris (β, β, γ-oximinoalkyl) amines from aliphatic nitro compounds and methyl vinyl ketone is described. The strategy involves N, N-bis (siloxy) enamines as key intermediates. The latter are accessible by double silylation of alkylnitro compounds. Nickel (II) and copper (II) complexes of tris (β, β, γ- oximinoalkyl) amines are prepared and structurally characterized.