Tetrahedron

Synthese totale du (±)-valerenal et de l'epi-6 β-(±)-valerenal

R Baudouy, J Sartoretti, F Choplin

文献索引：Baudouy,R.; Sartoretti,J.; Choplin,F. Tetrahedron, 1983 , vol. 39, p. 3293

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被引用次数: 21

摘要

(±)-Valérénal 1 and 6β-épi-(±)-valérenal 1'have been synthesized from 3-methyl cyclohexanone. The key steps are the vinylallenic 13 preparation and the conversion of this compound into substituted hydrindenones 15 et 15'by acetoxythallation.