Tetrahedron letters

A new route for the efficient synthesis of (±) ochromycinone, a naturally occurring benz [a] anthraquinone.

A Guingant, MM Barreto

文献索引：Guingant, Andre; Barreto, Marie Manuel Tetrahedron Letters, 1987 , vol. 28, # 27 p. 3107 - 3110

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被引用次数: 56

摘要

Few studies have attempted the total synthesis of these compounds 9, 12. Very recently, Sniecku! et al. described the first total synthesis of both ochromycinone 1 and its 0- methylated derivative X-14880 C 13. Their successful approach was based on the aromatic directed metalation strategy. In this communication we present a completely different approach which allows a concise synthesis of the target molecule. Our strategy, illustrated ...