Polyfluoro-compounds based on the cycloheptane ring system. Part 6. Bicyclic compounds derived from nonafluorocyclohepta-1, 3-dienes and from …

DJ Dodsworth, CM Jenkins, R Stephens…

文献索引：Dodsworth, David J.; Jenkins, Charles M.; Stephens, Robert; Tatlow, John Colin Journal of Fluorine Chemistry, 1984 , vol. 24, p. 509 - 522

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被引用次数: 6

摘要

Abstract 1H-, 2H-, and 5H-Nonafluoro-and 1H, 4H-octafluoro-cyclohepta-1, 3 diene afforded the corresponding H-substituted polyfluorobicyclo (3, 2, 0)-hept-6-enes by cross-ring bond formation between positions 1 and 4. Octafluorocyclohepta-1, 3, 5-triene similarly gave octafluorobicyclo-(3, 2, 0) hepta-2, 6-diene. By passage over cobalt (III) fluoride at 100 C, the 1H-bicyclo-6-ene gave 1H-undecafluorobicyclo (3, 2, 0) heptane and thence the ...