Synlett

α-Oxygen-atom Induced Methylenation of Ketones by CH2 (ZnI) 2

…, D Arioka, H Yoshino, H Fushimi, H Fushini, K Oshima…

文献索引：Ukai; Arioka; Yoshino; Fushimi; Oshima; Utimoto; Matsubara Synlett, 2001 , # 4 p. 513 - 514

全文：HTML全文

被引用次数: 15

摘要

Abstract: Ketones bearing a hetero-atom at a-position were methylenated selectively by CH2 (ZnI) 2 to give allylic alcohols; a nucleophilic attack of the zinc species was accelerated with a coordination of a hetero-atom at a-position. Key words: dimetal, methylenation, regioselective, zinc