Tetrahedron letters

Etude de la reactivite du tris (tertiobutyl) phenyldithiophosphorane

J Navech, M Revel, R Kraemer

文献索引：Navech, J.; Revel, M.; Kraemer, R. Tetrahedron Letters, 1985 , vol. 26, # 2 p. 207 - 210

全文：HTML全文

被引用次数: 17

摘要

Abstract Heating of tris (tertiobutyl) phenyldithiophosphorane gives rise to an isomer with a tetracoordinated phosphorus atom. The action of triphenylphosphine loads to a tricyclophosphathiane which can be transformed in diphosphene by an excess of triphenylphosphine. Reactions with various nucleophilic derivatives (pyridine, triethylamine, diethylamine, butylamine, water, tetraphenylarsonium chloride) are described.