Synthesis of 7-epineoptilocaulin, mirabilin B, and isoptilocaulin. A unified biosynthetic proposal for the ptilocaulin and batzelladine alkaloids. Synthesis and structure …

M Yu, SS Pochapsky, BB Snider

文献索引：Snider,B.B.; Faith,W.C. Journal of the American Chemical Society, 1984 , vol. 106, p. 1443 Full Text View citing articles Show Details Snider; Faith Tetrahedron Letters, 1983 , vol. 24, # 9 p. 861 - 864

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被引用次数: 29

摘要

Addition of guanidine to a 6-methylhexahydroindenone in MeOH at 85° C afforded 7- epineoptilocaulin. A similar reaction with a 6-propylhexahydroindenone afforded netamine E. MnO2 oxidation of 7-epineoptilocaulin and netamine E afforded mirabilin B and netamine