Ouverture par HF-pyridine d'aziridines tricycliques. III. Comparaison entre la reactivite des aziridines et celle des oxiranes

…, M Rouillard, M Decouzon, S Geribaldi

文献索引：Girault, Y.; Rouillard, M.; Decouzon, M.; Geribaldi, S. Journal of Fluorine Chemistry, 1990 , vol. 49, # 2 p. 231 - 246

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被引用次数: 5

摘要

Abstract The ring opening of 3-aza 1, 8, 8-trimethyl tricyclo [5.2. 1.0 2, 4] octane isomers by HF-pyridine has been studied. A series of γ-fluoroamines and non fluorinated amines, isomers of the starting aziridines, was obtained. No β-fluoroamines were isolated. The structures of diastereoisomeric amines, established by 1 H and 19 F NMR, show product structure dependence upon the exo-endo aziridine configuration. A comparison between ...