Influence of solvent polarity on the radiationless decay of the intramolecular exciplexes of. omega.-phenyl-. alpha.-(dimethylamino) alkanes

…, L Viaene, P Van Haver, FC De Schryver

文献索引：Auweraer, M. Van der; Viaene, L.; Haver, Ph. Van; Schryver, F. C. De Journal of Physical Chemistry, 1993 , vol. 97, # 28 p. 7178 - 7184

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被引用次数: 23

摘要

Using optoacoustic spectroscopy, the radiationless decay processes of intramolecular exciplexes of w-phenyl-aN, N-dimethylaminoalkanes are investigated. Upon increase of the solvent polarity, the relative efficiency of the intersystem crossing process from the singlet exciplex to the locally excited triplet decreases compared to the efficiency of the internal conversion process. These results can be rationalized in the framework of the current ...