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Synthetic communications

Convenient synthesis of oxazolidinones and oxazinones from allyl and homoallyl amines under mild conditions

E García??Egido, I Fernández, L Muñoz

文献索引:Garcia-Egido, Eduardo; Fernandez, Isabelle; Munoz, Luis Synthetic Communications, 2006 , vol. 36, # 20 p. 3029 - 3042

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被引用次数: 8

摘要

Abstract An efficient one??pot general method for the high??yield synthesis in solution of oxazolidinones and oxazinones from allyl??and homoallylamines, respectively, has been developed. The reaction is carried out at an atmospheric pressure between 0° C and room temperature using a solution of carbon dioxide in acetonitrile and hindered guanidine as the base.