Chemistry Letters

A new reaction of azidoformate with unsaturated ethers catalyzed by dichloro-bis (benzonitrile) palladium.

…, N Saitoh, H Iizuka, C Ogyu, M Kosugi, S Nakaido

文献索引：Migita, Toshihiko; Saitoh, Nobuhiro; Iizuka, Hisao,; Ogyu, Chikataka; Kosugi, Masanori; Nakaido, Setsuko Chemistry Letters, 1982 , p. 1015 - 1016

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被引用次数: 4

摘要

In the presence of dichloro-bis (benzonitrile) palladium, azidoformate reacts with various unsaturated ethers to give 1-alkoxy-1-carboalkoxyiminoalkanes. Reaction with 1-methyl-2- propenyl ether was accompaied by methyl migration, giving 1-alkoxy-1-carboalkoxyimino-2- methylpropane.