Preparation of Solid Salt??Stabilized Functionalized Organozinc Compounds and their Application to Cross??Coupling and Carbonyl Addition Reactions

…, G Manolikakes, T Kunz, P Knochel

文献索引：Bernhardt, Sebastian; Manolikakes, Georg; Kunz, Thomas; Knochel, Paul Angewandte Chemie - International Edition, 2011 , vol. 50, # 39 p. 9205 - 9209

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被引用次数: 42

摘要

Organozinc reagents have found numerous synthetic applications, especially in the Negishi cross-coupling reaction.[1, 2] Various methods for the preparation of organozinc compounds have been reported.[3] However, polyfunctional zinc reagents of type RZnX (X= halide)[4] or R2Zn are highly sensitive to moisture and air. These properties represent a serious drawback for their practical use in the laboratory and on an industrial scale. Thus, the ...