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Highly efficient cleavage of epoxides catalyzed by B (C 6 F 5) 3

S Chandrasekhar, CR Reddy, BN Babu…

文献索引:Chandrasekhar; Raji Reddy; Nagendra Babu; Chandrashekar Tetrahedron Letters, 2002 , vol. 43, # 21 p. 3801 - 3803

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被引用次数: 67

摘要

A highly effective protocol for ring opening of epoxides with allyl and propargyl alcohols, aniline and thiophenol in the presence of catalytic amounts of B (C6F5) 3 has been developed. Benzyl, tetrahydropyranyl, tert-butyldimethyl silyl protecting groups were stable under the reaction conditions.