Tetrahedron

The substitution of 5-halo-1, 2, 3-triazines with electrolytically generated superoxide

T Itoh, K Nagata, M Okada, H Takahashi, A Ohsawa

文献索引：Itoh, Takashi; Nagata, Kazuhiro; Okada, Mamiko; Takahashi, Hiroyuki; Ohsawa, Akio Tetrahedron, 1991 , vol. 47, # 25 p. 4317 - 4324

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被引用次数: 13

摘要

Electrolytically generated superoxide reacted with 5-halo-1, 2, 3-triazines 1 to afford 5- hydroxy-1, 2, 3-triazines 2. Reaction of 1 with hydroxide anion or potassium superoxide resulted in complicated mixture of products, therefore the reaction was specific for electrogenerated superoxide. The reaction mechanism was investigated with electrochemical methods, and it was revealed that one electron transfer from superoxide ...