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1, 3??Diethynylallenes: Stable Monomers, Length??Defined Oligomers, Asymmetric Synthesis, and Optical Resolution

…, P Schanen, P Seiler, F Diederich

文献索引:Ter Wiel, Matthijs K. J.; Odermatt, Severin; Schanen, Patrick; Seiler, Paul; Diederich, Francois European Journal of Organic Chemistry, 2007 , # 21 p. 3449 - 3462

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被引用次数: 10

摘要

Abstract A series of differently substituted 1, 3-diethynylallenes (DEAs) have been synthesized, confirming that the previously introduced construction protocols tolerate a variety of functional groups. The new DEAs bear at least one polar group to facilitate enantiomer separations on chiral stationary phases and to allow further functionalization. They are thermally and environmentally stable compounds since bulky substituents next ...