Ultraviolet photoelectron spectra of 2-norbornanone, 2, 5-norbornanedione, their alkyl derivatives and thio-analogues. An investigation of transannular interactions by …

…, NPC Westwood, NH Werstiuk

文献索引：Frost, David C.; Westwood, Nicholas P. C.; Werstiuk, Nick H. Canadian Journal of Chemistry, 1980 , vol. 58, p. 1659 - 1665

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被引用次数: 14

摘要

HeI photoelectron spectra are reported for a series of methyl-substituted monoketones and diketones based on 2-norbornanone. The effect of methyl substitution, and the inductive effect of a second carbonyl group has been studied. The diketones show a small separation between the two ketone moieties due to a through-bond interaction. Replacement with a thiocarbonyl group permits a comparison of the relative C= S and C= O interactions. The ...