Oxidatively assisted nucleophilic substitution of organosilicon iodides

AI Al-Wassil, C Eaborn, AK Saxena

文献索引：Al-Wassil, Abdulaziz I.; Eaborn, Colin; Saxena, Anil K. Journal of the Chemical Society, Chemical Communications, 1983 , # 17 p. 974 - 975

全文：HTML全文

被引用次数: 0

摘要

The iodides (Me3Si) 3CSiMe2I,(Me3Si) 3CSiPh2I, and But3SiL react with m- chloroperoxybenzoic acid to give the hydroxides (Me3Si) 3CSiMe2OH,(Me3Si) 2C (SiPh2Me)(SiMe2OH), and But3SiOH, respectively in MeOH (Me3Si) 3CSiPh2I suggests the participation of silico-cationic intermediates.