Journal of molecular structure

Matrix effects in the low-temperature ozonation of ethylene, tetramethylethylene and 1-hexene

U Samuni, Y Haas, R Fajgar, J Pola

文献索引：Samuni; Haas; Fajgar; Pola Journal of Molecular Structure, 1998 , vol. 449, # 2-3 p. 177 - 201

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被引用次数: 14

摘要

The ozonation of the title compounds was studied in argon and CO2 matrices at low temperatures (12–80K). All three were found to react with ozone in a CO2 matrix deposited at low temperature, and having an amorphous structure. The reaction was found to start at 26K, the temperature at which the matrix undergoes a phase transition. In contrast, only tetramethylethylene (TME) was found to react in an argon matrix, the other two ...