Macromolecules

In Situ Generated 1: 1 Zn (II)-Containing Polymer Complex Sensor for Highly Enantioselective Recognition of N-Boc-Protected Alanine

J Hou, F Song, L Wang, G Wei, Y Cheng, C Zhu

文献索引：Hou, Jiali; Song, Fengyan; Wang, Lu; Wei, Guo; Cheng, Yixiang; Zhu, Chengjian Macromolecules, 2012 , vol. 45, # 19 p. 7835 - 7842,8

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被引用次数: 23

摘要

A novel chiral (S)-BINAM-based fluorescence polymer sensor was designed and synthesized by the polymerization of 5, 5′-((2, 5-dioctyloxy-1, 4-phenylene) bis (ethyne-2, 1- diyl) bis (2-hydroxy-3-(piperidin-1-ylmethyl) benzaldehyde (M-1) with (S)-2, 2′- binaphthyldiamine (S-BINAM, M-2) via Schiff's base formation. The resulting chiral polymer sensor shows very weak fluorescence but exhibits the obvious fluorescence enhancement ...