Synthesis of molybdenum-rhodium and molybdenum-iridium compounds linked by a heterodifunctional ligand and formation of molybdenum-iridium dihydrides by …
CP Casey, RM Bullock, F Nief
文献索引：Casey,C.P.; Bullock,R.M.; Nief,F. Journal of the American Chemical Society, 1983 , vol. 105, p. 7574
Abstract: A series of Rh-Mo and Ir-Mo compounds linked by a heterodifunctional ligand have been prepared. Lic [v5-C5H4P (C6H4-p-CH3),] Mo (CO)~-(1) reacted with the chlorine- bridged rhodium dimer ([(C6H4-p-CH3) 2PCH2] 2RhC1J2 (2) to give [(C6H4-p-CH3), PCH2] 2RhMo (CO) 3 [~ 5-C5H4P (C6H4-p-CH3) z](3). Reaction of 1 with [(CO), RhCI], gave
