Copper-Catalyzed Nitrogen Transfer Mediated by Iodosylbenzene PhI O

P Dauban, L Sanière, A Tarrade…

文献索引：Dauban; Saniere; Tarrade; Dodd Journal of the American Chemical Society, 2001 , vol. 123, # 31 p. 7707 - 7708

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被引用次数: 238

摘要

Transition metal-catalyzed functionalization of hydrocarbons is a fundamental process of paramount importance in organic synthesis. Among the numerous existing methodologies, catalyzed atom transfer to olefins plays a pivotal role since it allows access to aziridines, 1amino alcohols, 2 diols, 2, 3 and epoxides. 1, 4 In the latter case, iodosylbenzene5 (PhIdO) 1 has been extensively used as a primary oxygen atom source in combination with ...