Oxidative Cleavage of Diselenide by m-Nitrobenzenesulfonyl Peroxide. Novel Method for the Electrophilic Benzeneselenenylations of Olefins and Aromatic Rings

M Yoshida, S Sasage, K Kawamura, T Suzuki…

文献索引：Yoshida, Masato; Sasage, Shuichi; Kawamura, Kyoko; Suzuki, Takashi; Kamigata, Nobumasa Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 2 p. 416 - 422

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被引用次数: 20

摘要

Diphenyl diselenide was found to be readily converted into benzeneselenenyl m- nitrobenzenesulfonate (PhSeOSO 2 C 6 H 4 NO 2-m) by treating with m- nitrobenzenesulfonyl peroxide. When the selenenyl sulfonate thus formed was allowed to react in situ with olefins, such as cyclohexene, 1-octene, or styrene, in the presence of various nucleophiles, the adducts of benzeneselenenyl group and a nucleophile were ...