Tetrahedron letters

One electron transfer reaction of phenyl vinyl sulfides with dioxygen. The fate of the intermediate vinyl sulfide radical cations.

L Benati, PC Montevecchi, D Nanni, P Spagnolo

文献索引：Benati; Montevecchi; Nanni; Spagnolo Tetrahedron Letters, 1993 , vol. 34, # 22 p. 3595 - 3598

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被引用次数: 4

摘要

Abstract Mild reaction of pheyl vinyl sulfides with dioxygen can lead to the eventual formation of rearranged vinyl sulfides and/or carbonyl-containing sulfide products, which are believed to result from decomposition of initially-formed vinyl sulfide radical cations. Supporting evidence is provided by the comparable findings obtained from the one electron oxidation of one vinyl sulfide by cerium (IV) ammonium nitrate.