The Journal of Organic Chemistry

Electron transfer in the decomposition of hexaalkylhydrazine dications

SF Nelsen, JT Ippoliti

文献索引：Nelsen, Stephen F.; Ippoliti, J. Thomas Journal of Organic Chemistry, 1986 , vol. 51, # 16 p. 3169 - 3176

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被引用次数: 6

摘要

Rearrangements of hexaalkylhydrazine dications [R3N+ N+ R3] to a-amino ammonium cations [R3N+ CHR'Nb] derived by Hofmann-like degradation (loss of an a proton and NN bond cleavage to give an amino immonium cation, followed by addition of the amino group to the C= N+ bond) are investigated. Tricyclic dications 62+ and lo2+ give 14'and 8+, respectively, showing high selectivity for hydrogen loss from the methylenes in the bicyclo ...