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Bis (pyridine) iodonium tetrafluoroborate (IPy2BF4): A versatile oxidizing reagent

J Barluenga, F González??Bobes…

文献索引:Barluenga, Jose; Gonzalez-Bobes, Francisco; Murguia, Marcelo C.; Ananthoju, Sreenivasa R.; Gonzalez, Jose M. Chemistry - A European Journal, 2004 , vol. 10, # 17 p. 4206 - 4213

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被引用次数: 47

摘要

Abstract The use of bis (pyridine) iodonium tetrafluoroborate (IPy 2 BF 4) as an oxidizing agent towards different types of alcohols is reported. The observed reactivity involves different reaction pathways, as a function both of the structures of the starting materials and of the experimental conditions. Interestingly, the title iodine-containing compound is capable of a tuneable reaction with simple cycloalkanols, providing straight and selective access ...